1. INTRODUCTION
It is estimated that 21 billion gallons of ballast taken on in foreign ports are discharged by commercial vessels annually in the waters of the United States (Carlton et al. 1993). Specifically, ballast water transport is a major vector for the introduction of potentially invasive aquatic species.

The concept to combat Aquatic Nuisance Species (ANS) invasion resulting from ballast water discharge, described in this paper, is a technical extension of MH Systems' American Underpressure System (AUPS). The AUPS utilizes a slight negative pressure in the tank's ullage space, in an inert environment, to prevent or minimize oil spillage from tankers (Husain et al. 2001).

The ballast water treatment method consists of bubbling the inert gas via a row of pipes (orifices at the bottom of the pipes) located at the bottom of the tank, while maintaining a negative pressures of -2 psi at the ullage space The inert gas from a standard shipboard inert gas generator is composed of 84% Nitrogen, 12-14% CO2 and 2% Oxygen. The ballast water will be equilibrated with gas from an inert gas generator. As a result, the water will become hypoxic, will contain CO2 levels much higher than normal, and the pH will drop from the normal pH of seawater (pH8) to approximately pH6.

This ballast water treatment system has undergone preliminary laboratory tests at the Scripps Institution of Oceanography. As expected, combination of hypoxia, pH decrease, and raised CO2 levels severely affected the specimens in the laboratory.


The paper is organized as follows. First, we give background information including practical requirements, current investigative efforts, and general theoretical considerations. Then we describe survivability experiments conducted at the Scripps Institution of Oceanography. This is followed by discussion of analysis and design considerations. In the final sections of the paper we describe the ballast water treatment system and provide a preliminary cost analysis.
2. BACKGROUND
2.1 Ballast Water Treatment Standards
Standards for treatment of ballast water are still in a state of flux. Efforts to define standards are ongoing in the US Congress, International Maritime Organization (IMO), and other individual maritime nations. The US Congress (NAISA 2002) proposes an Act that will, among other considerations, set the interim standards for ballast water treatment (BWT). It states, "The interim standard for BWT shall be a biological effectiveness of 95% reduction in aquatic vertebrates, invertebrates, phytoplankton and macroalgae." There are discussions about setting micron standards, i.e. x microns cut-off for living organisms. Currently, a fifty (50) micron standard is being discussed in various circles, including IMO and US Coast Guard. The default standard appears to be the Ballast Water Exchange (BWE), or something close to it. Cangelosi (2002) states "… the Coast Guard has set forth a "do-it-yourself" approach, directing interested ship owners to conduct complex shipboard experiments (post-installation) to undertake direct and real-time comparisons between BWE and treatment. If the comparison is favorable and defensible, the Coast Guard will approve the treatment. ….."
2.2 Current Investigative Efforts Of Alternative Technologies
Glosten (2002) provides a review of the numerous treatment systems options being investigated. These include heat, cyclonic separation, filtration, chemical biocides, ultraviolet light radiation, ultrasound, and magnetic/electric field. The methods not mentioned in this reference are hypoxia, carbonation, and their combination. In studies of 18 months duration on a coal/ore vessel (Tamburri et al. 2002), the ballast water dissolved O2 level was reduced and held to concentrations at or below 0.8 mg/l by bubbling essentially pure nitrogen. The experiments resulted in a treatment "that can dramatically reduce the survivorship of most organisms found in the ballast water…"

In extensive experiments with gas of varying percent CO2, N2 and O2 (McMahon 1995), the "…results indicate that CO2 injection may be an easily applied, cost-effective, environmentally acceptable molluscicide for mitigation and control a raw water system macrofouling by Asian clams and zebra mussels".
2.3 Corrosion Considerations Of Various Treatment Systems
Shipboard corrosion mitigation is always a priority consideration. It requires the continual attention of the crew and, if not carefully controlled, can actually compromise the strength of the ship. Any installed ballast water treatment system must not under any circumstances increase the potential for corrosion and, if possible, should decrease the potential. The system discussed in this proposal has considered the corrosion issue. As reported in literature Tamburri et al. (2002), corrosion might even be mitigated by deoxygenation. Perry et al. (1984) states that unless pH level drops below 4, concerns about corrosion are unfounded.
 
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